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IB Chemistry
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Chemistry SL
6 topics41 outcomesLocal syllabus version: 2025
S1: Models of the Particulate Nature of Matter
6 outcomes
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S1: Models of the Particulate Nature of Matter
6 outcomes
- S1.1.1Describe the nuclear model of the atom: protons and neutrons in a nucleus surrounded by electrons; define atomic number, mass number, and isotopes
- S1.1.2Calculate relative atomic mass from isotopic masses and abundances; describe how a mass spectrometer separates ions by mass-to-charge ratio
- S1.2.1Describe the electromagnetic spectrum and explain how atomic emission and absorption line spectra provide evidence for discrete electron energy levels
- S1.2.2Write electron configurations for elements and ions up to Z = 36 using sublevel (s, p, d) notation; apply the Aufbau principle, Hund's rule, and Pauli exclusion principle
- S1.3.1Apply the mole concept: use the Avogadro constant (6.022 × 10²³ mol⁻¹) to interconvert between amount of substance, number of particles, and molar mass
- S1.3.2Determine empirical and molecular formulae from percentage composition data and combustion analysis results
S2: Models of Bonding and Structure
7 outcomes
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S2: Models of Bonding and Structure
7 outcomes
- S2.1.1Describe ionic bonding as electrostatic attraction between oppositely charged ions; explain lattice structure and relate properties (melting point, conductivity) to ionic bonding
- S2.2.1Describe covalent bonding as the sharing of electron pairs; draw Lewis (electron dot) structures for molecules and polyatomic ions
- S2.2.2Predict and explain the shapes and bond angles of molecules and ions (linear, trigonal planar, tetrahedral, trigonal bipyramidal, octahedral) using VSEPR theory
- S2.2.3Distinguish between polar and non-polar bonds using electronegativity differences; determine the polarity of molecules from their geometry
- S2.3.1Describe metallic bonding as the electrostatic attraction between a lattice of cations and a sea of delocalised electrons; relate to physical properties of metals
- S2.4.1Compare the four types of solid structure (ionic, metallic, covalent network, molecular) and relate their structures to physical properties
- S2.4.2Describe London dispersion forces, dipole-dipole attractions, and hydrogen bonding; explain their influence on physical properties such as boiling points and solubility
S3: Classification of Matter
5 outcomes
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S3: Classification of Matter
5 outcomes
- S3.1.1Explain the organisation of the periodic table by increasing atomic number; identify patterns in physical and chemical properties across periods and down groups
- S3.1.2Explain trends in atomic radius, ionic radius, electronegativity, electron affinity, and ionisation energies across periods and down groups
- S3.2.1Name and draw structural formulae for the major homologous series: alkanes, alkenes, alkynes, arenes, halogenoalkanes, alcohols, aldehydes, ketones, carboxylic acids, esters, amines, and amides
- S3.2.2Identify structural isomers (chain, position, and functional group) and stereoisomers (cis/trans and optical) for organic compounds
- S3.2.3Predict physical and chemical properties of organic compounds from their functional groups and carbon skeleton
R1: What Drives Chemical Reactions?
6 outcomes
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R1: What Drives Chemical Reactions?
6 outcomes
- R1.1.1Define enthalpy change (ΔH) and distinguish between exothermic and endothermic reactions; calculate ΔH from calorimetric data using q = mcΔT
- R1.1.2Calculate standard enthalpy changes using Hess's law and standard enthalpies of formation (ΔfH°) or combustion (ΔcH°)
- R1.1.3Estimate enthalpy changes using average bond enthalpies and explain why calculated values differ from experimental values
- R1.3.1Compare energy density and combustion products of different fuels (hydrogen, hydrocarbons, biofuels) and evaluate their suitability as energy sources
- R1.4.1Define entropy (S) and explain how dispersal of energy and matter contribute to an increase in entropy in physical and chemical processes
- R1.4.2Calculate Gibbs free energy change (ΔG = ΔH − TΔS) and use its sign to predict whether a reaction is spontaneous under given conditions
R2: How Much, How Fast, and How Far?
8 outcomes
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R2: How Much, How Fast, and How Far?
8 outcomes
- R2.1.1Balance chemical equations and use stoichiometric mole ratios to calculate masses, volumes, and amounts of reactants and products
- R2.1.2Identify the limiting reagent in a reaction; calculate theoretical yield, actual yield, and percentage yield
- R2.1.3Perform solution stoichiometry calculations involving concentration (mol dm⁻³), dilution, and acid-base titrations
- R2.2.1Define rate of reaction; describe experimental methods for monitoring reaction rate (gas volume, mass loss, colour change, conductivity)
- R2.2.2Explain collision theory and the effect of concentration, temperature, surface area, pressure (for gases), and catalysts on reaction rate using Maxwell-Boltzmann distributions
- R2.3.1Define dynamic equilibrium; describe the characteristics of a system at equilibrium in terms of equal forward and reverse rates
- R2.3.2Apply Le Chatelier's principle to predict the effect of changes in concentration, pressure/volume, temperature, and addition of a catalyst on the position of equilibrium
- R2.3.3Write the equilibrium constant expression Kc for homogeneous equilibria and calculate Kc from equilibrium concentrations
R3: What Are the Mechanisms of Chemical Change?
9 outcomes
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R3: What Are the Mechanisms of Chemical Change?
9 outcomes
- R3.1.1Apply the Brønsted-Lowry theory to identify acids (proton donors), bases (proton acceptors), and conjugate acid-base pairs in reactions
- R3.1.2Distinguish between strong and weak acids/bases; calculate pH and pOH from [H⁺] and [OH⁻] concentrations using Kw = 1.0 × 10⁻¹⁴ at 25 °C
- R3.1.3Calculate pH of weak acids and bases using Ka and Kb values; derive the relationship pKa + pKb = pKw
- R3.1.4Describe acid-base titration curves for strong/weak acid and strong/weak base combinations; identify the equivalence point and choose an appropriate indicator
- R3.2.1Define oxidation and reduction in terms of electron transfer and changes in oxidation state; identify oxidising and reducing agents and balance redox equations
- R3.2.2Describe the operation of a voltaic (galvanic) cell including electrodes, salt bridge, and direction of electron and ion flow
- R3.2.3Calculate cell potential E°cell = E°cathode − E°anode using standard electrode potentials; predict spontaneity of redox reactions
- R3.3.1Describe free-radical reactions (homolytic bond cleavage), including the initiation, propagation, and termination steps of the halogenation of alkanes
- R3.4.1Describe electrophilic addition reactions of alkenes with H₂, X₂, HX (Markovnikov's rule), and H₂O; explain the mechanism using curly arrows
Chemistry HL
6 topics64 outcomesLocal syllabus version: 2025
S1: Models of the Particulate Nature of Matter
9 outcomes
OpenClose
S1: Models of the Particulate Nature of Matter
9 outcomes
- S1.1.1Describe the nuclear model of the atom: protons and neutrons in a nucleus surrounded by electrons; define atomic number, mass number, and isotopes
- S1.1.2Calculate relative atomic mass from isotopic masses and abundances; describe how a mass spectrometer separates ions by mass-to-charge ratio
- S1.2.1Describe the electromagnetic spectrum and explain how atomic emission and absorption line spectra provide evidence for discrete electron energy levels
- S1.2.2Write electron configurations for elements and ions up to Z = 36 using sublevel (s, p, d) notation; apply the Aufbau principle, Hund's rule, and Pauli exclusion principle
- S1.2.3Explain trends in first ionisation energy across periods and down groups in terms of nuclear charge, shielding, and atomic radius HL only
- S1.2.4Describe the shapes and relative energies of s, p, and d orbitals; explain hybridisation (sp, sp², sp³) and its application to molecular geometry HL only
- S1.3.1Apply the mole concept: use the Avogadro constant (6.022 × 10²³ mol⁻¹) to interconvert between amount of substance, number of particles, and molar mass
- S1.3.2Determine empirical and molecular formulae from percentage composition data and combustion analysis results
- S1.4.1Apply the ideal gas law PV = nRT to solve problems involving pressure, volume, temperature, and amount of gas; describe deviations of real gases from ideal behaviour HL only
S2: Models of Bonding and Structure
10 outcomes
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S2: Models of Bonding and Structure
10 outcomes
- S2.1.1Describe ionic bonding as electrostatic attraction between oppositely charged ions; explain lattice structure and relate properties (melting point, conductivity) to ionic bonding
- S2.1.2Apply the Born-Haber cycle to calculate lattice enthalpies of ionic compounds, using Hess's law and standard enthalpy data HL only
- S2.2.1Describe covalent bonding as the sharing of electron pairs; draw Lewis (electron dot) structures for molecules and polyatomic ions
- S2.2.2Predict and explain the shapes and bond angles of molecules and ions (linear, trigonal planar, tetrahedral, trigonal bipyramidal, octahedral) using VSEPR theory
- S2.2.3Distinguish between polar and non-polar bonds using electronegativity differences; determine the polarity of molecules from their geometry
- S2.2.4Describe sigma (σ) and pi (π) bonds in terms of orbital overlap; explain resonance and delocalisation using formal charge analysis HL only
- S2.2.5Apply molecular orbital theory to describe bonding and antibonding orbitals in diatomic molecules; predict bond order and magnetic properties HL only
- S2.3.1Describe metallic bonding as the electrostatic attraction between a lattice of cations and a sea of delocalised electrons; relate to physical properties of metals
- S2.4.1Compare the four types of solid structure (ionic, metallic, covalent network, molecular) and relate their structures to physical properties
- S2.4.2Describe London dispersion forces, dipole-dipole attractions, and hydrogen bonding; explain their influence on physical properties such as boiling points and solubility
S3: Classification of Matter
7 outcomes
OpenClose
S3: Classification of Matter
7 outcomes
- S3.1.1Explain the organisation of the periodic table by increasing atomic number; identify patterns in physical and chemical properties across periods and down groups
- S3.1.2Explain trends in atomic radius, ionic radius, electronegativity, electron affinity, and ionisation energies across periods and down groups
- S3.1.3Describe the characteristic properties of transition metals: variable oxidation states, coloured compounds, catalytic activity, and complex ion formation HL only
- S3.1.4Explain the colour of transition metal complexes using crystal field theory (d-orbital splitting); describe the effect of ligand type on colour and stability HL only
- S3.2.1Name and draw structural formulae for the major homologous series: alkanes, alkenes, alkynes, arenes, halogenoalkanes, alcohols, aldehydes, ketones, carboxylic acids, esters, amines, and amides
- S3.2.2Identify structural isomers (chain, position, and functional group) and stereoisomers (cis/trans and optical) for organic compounds
- S3.2.3Predict physical and chemical properties of organic compounds from their functional groups and carbon skeleton
R1: What Drives Chemical Reactions?
8 outcomes
OpenClose
R1: What Drives Chemical Reactions?
8 outcomes
- R1.1.1Define enthalpy change (ΔH) and distinguish between exothermic and endothermic reactions; calculate ΔH from calorimetric data using q = mcΔT
- R1.1.2Calculate standard enthalpy changes using Hess's law and standard enthalpies of formation (ΔfH°) or combustion (ΔcH°)
- R1.1.3Estimate enthalpy changes using average bond enthalpies and explain why calculated values differ from experimental values
- R1.2.1Apply Hess's law in energy cycles; calculate lattice enthalpies and enthalpies of solution using Born-Haber and energy cycles HL only
- R1.3.1Compare energy density and combustion products of different fuels (hydrogen, hydrocarbons, biofuels) and evaluate their suitability as energy sources
- R1.4.1Define entropy (S) and explain how dispersal of energy and matter contribute to an increase in entropy in physical and chemical processes
- R1.4.2Calculate Gibbs free energy change (ΔG = ΔH − TΔS) and use its sign to predict whether a reaction is spontaneous under given conditions
- R1.4.3Relate ΔG° to the equilibrium constant K using ΔG° = −RT ln K, and interpret the relationship between thermodynamics and the position of equilibrium HL only
R2: How Much, How Fast, and How Far?
13 outcomes
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R2: How Much, How Fast, and How Far?
13 outcomes
- R2.1.1Balance chemical equations and use stoichiometric mole ratios to calculate masses, volumes, and amounts of reactants and products
- R2.1.2Identify the limiting reagent in a reaction; calculate theoretical yield, actual yield, and percentage yield
- R2.1.3Perform solution stoichiometry calculations involving concentration (mol dm⁻³), dilution, and acid-base titrations
- R2.2.1Define rate of reaction; describe experimental methods for monitoring reaction rate (gas volume, mass loss, colour change, conductivity)
- R2.2.2Explain collision theory and the effect of concentration, temperature, surface area, pressure (for gases), and catalysts on reaction rate using Maxwell-Boltzmann distributions
- R2.2.3Derive the rate expression (rate law) from experimental data; determine reaction orders and the rate constant k HL only
- R2.2.4Use the Arrhenius equation (k = Ae^(−Ea/RT)) to calculate activation energy from rate constant data at different temperatures HL only
- R2.2.5Identify the rate-determining step from a proposed reaction mechanism and verify consistency with the observed rate expression HL only
- R2.3.1Define dynamic equilibrium; describe the characteristics of a system at equilibrium in terms of equal forward and reverse rates
- R2.3.2Apply Le Chatelier's principle to predict the effect of changes in concentration, pressure/volume, temperature, and addition of a catalyst on the position of equilibrium
- R2.3.3Write the equilibrium constant expression Kc for homogeneous equilibria and calculate Kc from equilibrium concentrations
- R2.3.4Write and use Kp expressions for gaseous equilibria; interconvert Kc and Kp HL only
- R2.3.5Use the reaction quotient Q to predict the direction in which a reaction will proceed towards equilibrium HL only
R3: What Are the Mechanisms of Chemical Change?
17 outcomes
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R3: What Are the Mechanisms of Chemical Change?
17 outcomes
- R3.1.1Apply the Brønsted-Lowry theory to identify acids (proton donors), bases (proton acceptors), and conjugate acid-base pairs in reactions
- R3.1.2Distinguish between strong and weak acids/bases; calculate pH and pOH from [H⁺] and [OH⁻] concentrations using Kw = 1.0 × 10⁻¹⁴ at 25 °C
- R3.1.3Calculate pH of weak acids and bases using Ka and Kb values; derive the relationship pKa + pKb = pKw
- R3.1.4Describe acid-base titration curves for strong/weak acid and strong/weak base combinations; identify the equivalence point and choose an appropriate indicator
- R3.1.5Explain the composition and action of buffer solutions; calculate buffer pH using the Henderson-Hasselbalch equation HL only
- R3.1.6Apply the Lewis theory to identify acids (electron pair acceptors) and bases (electron pair donors), extending to reactions not covered by Brønsted-Lowry HL only
- R3.2.1Define oxidation and reduction in terms of electron transfer and changes in oxidation state; identify oxidising and reducing agents and balance redox equations
- R3.2.2Describe the operation of a voltaic (galvanic) cell including electrodes, salt bridge, and direction of electron and ion flow
- R3.2.3Calculate cell potential E°cell = E°cathode − E°anode using standard electrode potentials; predict spontaneity of redox reactions
- R3.2.4Apply ΔG° = −nFE° to relate thermodynamics and electrochemistry; use Faraday's laws to calculate mass deposited or gas evolved during electrolysis HL only
- R3.2.5Describe the products of electrolysis of aqueous and molten electrolytes; explain the factors that determine electrode products HL only
- R3.3.1Describe free-radical reactions (homolytic bond cleavage), including the initiation, propagation, and termination steps of the halogenation of alkanes
- R3.4.1Describe electrophilic addition reactions of alkenes with H₂, X₂, HX (Markovnikov's rule), and H₂O; explain the mechanism using curly arrows
- R3.4.2Describe nucleophilic substitution of halogenoalkanes (SN1 and SN2); explain factors affecting which mechanism predominates HL only
- R3.4.3Describe electrophilic aromatic substitution (nitration, halogenation, Friedel-Crafts) of benzene and explain the role of the activating/deactivating substituent effects HL only
- R3.4.4Design multi-step organic synthesis routes, using retrosynthetic analysis, for target molecules from given starting materials HL only
- R3.4.5Interpret IR, ¹H NMR, and mass spectra to identify functional groups, molecular fragments, and determine structures of organic compounds HL only